Spraying water/methanol is so retro, like from the 80's dude. Get with the program and
get an intercooler.
Spraying water makes steam - thats cool (well the air is cooler) but the problem is steam is superheated water vapor, and it don't contribute to making power, it just displaces air. You get less air charge in as some is displaced by the steam, hence less power for the same boost (compared to using an intercooler). There is an advantage if the water vapour enters the combustion chamber in that on combustion it adds pressure by forming steam but compared to petrol/air combustion pressure it's bugger all.
Methanol is not much better, it displaces air too when turning to vapor but since it has an OH molecule it burns itself so does contribute to power. The energy released in this process would be less than the energy if you had the equivalent intercooled air and petrol though. It is highly corrosive so I would make it a 50/50 mix and make sure you keep it from leaking into the engine!
If you inject NO2, thats a different story as you should already know it does the same thing as the water injection (ie - cools the charge) but it also adds lots of oxygen to the mix, so you just need to add some more fuel.
I guess if you want to continue with it you need to be able to remotely adjust the amount of water/methanol mix and boost as you go, you will find a balance point where the engine won't take any more of either. The problem doing this is that at high engine speed the detonation will not be audible and will result in damaged pistons, even broken ring lands so be careful.
Regards
Daniel